Geo quick facts: Hartsville is the largest city in Darlington County, South Carolina, United States. It was chartered on December 11, 1891. The population was 7,764 at the 2010 census. Hartsville was chosen as an All-America City in 1996 and again in 2016. Hartsville has also been a National Arbor Day Foundation Tree City since 1986 – Wikipedia.
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